Valparin

KEDIA CHEMICALS
VALPROIC ACID


MSDS

CHEMICAL PRODUCT & COMPANY IDENTIFICATION

Supplier Name Kedia Chemical Industries Ltd.
Supplier Address 53/B Mittal Court, 224 Nariman Point, Mumbai 400021, India.
Fax Number +91-22-2826376.
Telephone Number +91-22-2040596.
Trade Name : Valproic Acid
Chemical name

Dipropyl acetic acid, 2-Propylpentanoic acid

Chemical formula C8H16O2
CAS No. 99-66-1


COMPOSITION /INFORMATION ON INGREDIENTS

Chemical Name CAS Risk Phrases EINECS Assay
2-Propylpentanoic acid 99-66-1 22 36/37/38 202-777-3 99%

Hazard Symbols                   : XN
 

HAZARDS IDENTIFICATION

Appearance Clear colorless liquid.
Eye Contact with eyes may cause severe irritation, and  possible eye burns.
Skin

May cause severe irritation and possible burns.

Inhalation May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breathe and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic Not available
Ingestion Not available



FIRST AID MEASURES

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing  contaminated clothing and shoes.

Eye Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids
Ingetion NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.
Inhalation Remove from exposure to fresh air immediately.
Note to Physician

Treat symptomatically and supportively.


FIRE FIGHTING MEASURES

General Information As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Auto ignition Temperature Not available
Flash Point 111o C ( 231.80 o F)
NFPA Rating Not published
Explosion Limits, Lower Not available
Explosion Limits, Upper Not available




ACCIDENTAL RELEASE MEASURES

General Information

Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

SPECIAL PRECAUTIONS

Precaution to be taken during handling and storing

Handling Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood
Storage  Store in tightly closed containers in a well ventilated place.


EXPOSURE CONTROLS/PERSONAL PROTECTION 

Engineering Controls Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible limits.
Exposure Limits


PERSONAL PROTECTIVE EQUIPMENT

Eyes Wear safety glasses and chemical goggles if splashing is possible
Skin Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing Wear appropriate protective clothing to minimize contact with skin.
Respirators Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.



PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid
Appearance Clear, colorless to light yellow
Odor None reported
Vapor Pressure     Not available
Vapor Density None available
Evaporation Rate Not available
Flash Point 111oC (231.8oF)
Viscosity Not available
Boiling Point 220 deg C @ 760.00 mm. Hg.
Freezing/Melting Point Not available
Decomposition Temperature

Not available

Solubility Slightly soluble in water
Specific Gravity/Density 0.9210 g/cm3
Molecular Formula C8H16O2
Molecular Weight 144.21

STABILITY AND REACTIVITY 

Chemical Stability Stable under normal temperatures and pressures.
Conditions to avoid Not available.
Incompatibilities with Other Materials Bases - oxidizing agents reducing agents.
Hazardous decomposition products Carbon monoxide, carbon dioxide.
Hazardous Polymerization Has not been reported.

TOXICOLOGICAL INFORMATION

Toxicity Data
RTECS# CAS# 99-66-1: YV7875000
LD50/LC50

CAS# 99-66-1: Oral, mouse: LD50 = 1098 mg/kg;  Oral,  rat: LD50 =670 /kg.

Carcinogenicity

: 2-Propylpentanoic acid, 99% - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.


ECOLOGICAL INFORMATION

Material Safety Data Sheet
Ecotoxicity                                            : Not available.

Disposal consideration
Dispose off in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants : None listed.
RCRA D-Series Chronic Toxicity Reference Levels              : None listed.
RCRA F-Series                                                                            : None listed.
RCRA P-Series                                                                            : None listed.
RCRA U-Series                                                                           : None listed.

Not listed as a material banned from land disposal according to RCRA.


TRANSPORT INFORMATION
US DOT
Shipping Name                     : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class                         : 8
UN Number                           : 3265
Packing Group                      : III

IMO
Shipping Name                     : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class                         : 8
UN Number                           : 3265
Packing Group                      : III

IATA
Shipping Name                     : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class                         : 8
UN Number                           : 3265
Packing Group                      : III

 RID/ADR
Shipping Name                     : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Dangerous Goods Code     : 8(40oC)
UN Number                           : 3265

Canadian TDG No information available.

REGULATORY INFORMATION
US FEDERAL TSCA
CAS# 99-66-1 is not listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules:-None of the chemicals in this product are under a Chemical Test Rule.
Section 12b:-None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: - None of the chemicals in this material have a SNUR under TSCA.SARA

Section 302 (RQ) :-None of the chemicals in this material have an RQ.
Section 302 (TPQ) :- None of the chemicals in this product have a TPQ.
Section 313 :-No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1/Class 2 Ozone depletors.
Clean Water Act: None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as Priority
Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
STATE 2-Propylpentanoic acid, 99% can be found on the following state right to know lists: Massachusetts.

WARNING: This product contains 2-Propylpentanoic acid, 99%, a chemical known to the state of California to cause birth defects or other reproductive harm.

California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases: R 22 Harmful if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 99-66-1: No information available.
Canada None of the chemicals in this product is listed on the DSL/NDSL list.
WHMIS: Not available. CAS# 99-66-1 is not listed on Canada's Ingredient
Disclosure List. Exposure Limits


OTHER INFORMATION

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information. Users should make investigations to determine the suitability of the information for their particular purpose. In no way shall we be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if we have been advised of possibility of such damages.                               

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