Benzyl phenylformate

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                      **** MATERIAL SAFETY DATA SHEET ****

  1-Bromo-3-chloropropane, 99%

        **** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: 1-Bromo-3-chloropropane, 99%
Catalog Numbers:
     10686-0000, 10686-0010, 10686-2500
Synonyms:
     Trimethylene chlorobromide
Company Identification (Europe):  Acros Organics BVBA
                                  Janssen Pharmaceuticalaan 3a
                                  2440 Geel, Belgium
Company Identification (USA):     Acros Organics
                                  One Reagent Lane
                                  Fairlawn, NJ  07410
For information in North America, call:   800-ACROS-01
For information in Europe, call:          0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call:     0032(0) 14575299

          **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+-----------+---------------+
|      CAS#      |              Chemical Name           |    %     |  EINECS#  |Haz Symbols| Risk Phrases  |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
|      109-70-6  |1-Bromo-3-chloropropane               |   99%    | 203-697-1 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
          Hazard Symbols: XN
          Risk Phrases: 20/21/22 36/37/38

                  **** SECTION 3 - HAZARDS IDENTIFICATION ****

                               EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.

Potential Health Effects
     Eye:
          Causes eye irritation.  Causes redness and pain.
     Skin:
          Causes skin irritation. Harmful if absorbed through the skin.
     Ingestion:
          Harmful if swallowed. May cause irritation of the digestive tract.
          May cause gastrointestinal irritation with nausea, vomiting and
          diarrhea. May cause liver and kidney damage.
     Inhalation:
          Harmful if inhaled. Causes respiratory tract irritation. May cause
          respiratory difficulty and coughing. Inhalation may cause nausea and
          headache.
     Chronic:
          Not available.

                    **** SECTION 4 - FIRST AID MEASURES ****

     Eyes:
          Flush eyes with plenty of water for at least 15 minutes,
          occasionally lifting the upper and lower eyelids. Get medical aid.
     Skin:
          Get medical aid. Flush skin with plenty of water for at least 15
          minutes while removing contaminated clothing and shoes.
     Ingestion:
          Get medical aid. Wash mouth out with water.
     Inhalation:
          Remove from exposure and move to fresh air immediately. If not
          breathing, give artificial respiration. If breathing is difficult,
          give oxygen. Get medical aid.
     Notes to Physician:

                  **** SECTION 5 - FIRE FIGHTING MEASURES ****

     General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear. Combustible liquid.
     Extinguishing Media:
          Use water spray, dry chemical, carbon dioxide, or chemical foam.

                **** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

     General Information: Use proper personal protective equipment as indicated
                          in Section 8.
     Spills/Leaks:
          Absorb spill with inert material (e.g. vermiculite, sand or earth),
          then place in suitable container.

                   **** SECTION 7 - HANDLING and STORAGE ****

     Handling:
          Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
          and eyes.
     Storage:
          Keep away from sources of ignition. Store in a cool, dry place.
          Store in a tightly closed container.

          **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

     Engineering Controls:
          Facilities storing or utilizing this material should be equipped
          with an eyewash facility and a safety shower. Use adequate
          ventilation to keep airborne concentrations low.
     Personal Protective Equipment

                 Eyes:
                       Wear chemical goggles.
                 Skin:
                       Wear appropriate protective gloves to prevent skin
                       exposure.
             Clothing:
                       Wear appropriate protective clothing to prevent skin
                       exposure.
          Respirators:
                       Follow the OSHA respirator regulations found in 29
                       CFR 1910.134 or European Standard EN 149. Always use
                       a NIOSH or European Standard EN 149 approved
                       respirator when necessary.

             **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State:             Clear liquid
Color:                      Not available.
Odor:                       chloroform-like - sweetish odor
pH:                         Not available.
Vapor Pressure:             6.6mbar @20 deg C
Viscosity:                  Not available.
Boiling Point:              142 - 145 deg C
Freezing/Melting Point:     -59 deg C
Autoignition Temperature:   Not available.
Flash Point:                81 deg C ( 177.80 deg F)
Explosion Limits, lower:    Not available.
Explosion Limits, upper:    Not available.
Decomposition Temperature:
Solubility in water:        Insoluble.
Specific Gravity/Density:   1.590
Molecular Formula:          C3H6BrCl
Molecular Weight:           157.44

                 **** SECTION 10 - STABILITY AND REACTIVITY ****

     Chemical Stability:
          Stable under normal temperatures and pressures.
     Conditions to Avoid:
          Incompatible materials, heat.
     Incompatibilities with Other Materials:
          Oxidizing agents, strong bases, aluminum, magnesium, zinc.
     Hazardous Decomposition Products:
          Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide,
          hydrogen bromide.
     Hazardous Polymerization: Will not occur.

                **** SECTION 11 - TOXICOLOGICAL INFORMATION ****

     RTECS#:
          CAS# 109-70-6: TX4113000
     LD50/LC50:
          CAS# 109-70-6: Inhalation, rat: LC50 = 5668 mg/m3; Inhalation, rat:
          LC50 = 6500 mg/m3/4H; Oral, mouse: LD50 = 1290 mg/kg; Oral, rat:
          LD50 = 930 mg/kg.
          Skin, rat: LD50 = 1600 mg/kg
Inhalation, rat: LC5O = 6.5 mg/l/4H
     Carcinogenicity:
       1-Bromo-3-chloropropane -
          Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
          See actual entry in RTECS for complete information.

                  **** SECTION 12 - ECOLOGICAL INFORMATION ****

     Ecotoxicity:
          Fish: Goldfish: LC50: 75 mg/l; 24 H; .Log Pow: 2.18

                 **** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

                  **** SECTION 14 - TRANSPORT INFORMATION ****

     IATA
          Shipping Name: 1-BROMO-3-CHLOROPROPANE
           Hazard Class: 6.1
              UN Number: 2688
          Packing Group: III
     IMO
          Shipping Name: 1-BROMO-3-CHLOROPROPANE
           Hazard Class: 6.1
              UN Number: 2688
          Packing Group: III
     RID/ADR
          Shipping Name: 1-BROMO-3-CHLOROPROPANE
           Hazard Class: 6.1
              UN Number: 2688
          Packing group: III

                  **** SECTION 15 - REGULATORY INFORMATION ****

 European/International Regulations
     European Labeling in Accordance with EC Directives
          Hazard Symbols: XN
          Risk Phrases:
                       R 20/21/22  Harmful by inhalation, in contact with
                       skin and if swallowed.
                       R 36/37/38  Irritating to eyes, respiratory system
                       and skin.
          Safety Phrases:
                       S 26  In case of contact with eyes, rinse immediately
                       with plenty of water and seek medical advice.
                       S 36/37/39  Wear suitable protective clothing, gloves
                       and eye/face protection.
                       S 45  In case of accident or if you feel unwell, seek
                       medical advice immediately (show the label where
                       possible).
   WGK (Water Danger/Protection)
          CAS# 109-70-6: 3
   United Kingdom Occupational Exposure Limits

   United Kingdom Maximum Exposure Limits

   Canada
          CAS# 109-70-6 is listed on Canada's DSL List.
          CAS# 109-70-6 is listed on Canada's Ingredient Disclosure List.
   Exposure Limits
          CAS# 109-70-6: OEL-RUSSIA:STEL 3 mg/m3
 US FEDERAL
     TSCA
          CAS# 109-70-6 is listed on the TSCA inventory.

                  **** SECTION 16 - ADDITIONAL INFORMATION ****

     MSDS Creation Date: 10/08/1998  Revision #1 Date: 10/28/2003

     The information above is believed to be accurate and represents the best
     information currently available to us. However, we make no warranty of
     merchantability or any other warranty, express or implied, with respect to
     such information, and we assume no liability resulting from its use. Users
     should make their own investigations to determine the suitability of the
     information for their particular purposes. In no way shall the company be
     liable for any claims, losses, or damages of any third party or for lost
     profits or any special, indirect, incidental, consequential or exemplary
     damages, howsoever arising, even if the company has been advised of
     the possibility of such damages.
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